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eXo Portal 3.5 supports the Kerberos authentication on a Microsoft Active Directory. You will need to configure both your Active Directory server and the application server.
The implementation makes possible to use SPNEGO or NTLM. The client will get two authentication headers, including Negotiate and NTLM and will use whichever supported by the browser. In Firefox, it is possible to manage authentication types, but it is not in Internet Explorer; therefore, SPNEGO will be used.
To learn more about how to configure Kerberos SSO, see here.